Superconductivity in lithium now has the highest demonstrated transition
temperature of any element, 20 K. Great pressure, 48 GPa, was needed
to achieve superconductivity.
According to the physicists at the University of Tokyo and Osaka University
who performed the experiment on lithium (the sample and its electrical
leads are squeezed in a diamond anvil press), their result bears out
an expectation that lighter elements should possess higher transition
temperatures.
Extrapolating this principle further, they argue, might produce room
temperature superconductivity in hydrogen, but only at crushing pressures
above 400 GPa. (Shimizu et al., Nature,
10 October 2002.)