pitchblende sample
This pitchblende sample was instrumental in the discovery of radium and polonium. Another picture

READ Curie's words

Research Breakthroughs

The Discovery of Polonium and Radium

PIERRE WAS SO INTRIGUED by Marie's work that he joined forces with her. Her research had revealed that two uranium ores, pitchblende and chalcolite, were much more radioactive than pure uranium itself.

She concluded that the highly radioactive nature of these ores might be due to one or more additional, as yet undiscovered, radioactive elements. Pierre put aside his research on crystals to help expedite Marie's discovery of the possible new elements. They worked as a team, each taking on specific scientific tasks.

“Neither of us could foresee that in beginning this work we were to enter the path of a new science which we should follow for all our future.”

It was far from easy to track down the new radioactive elements. Pitchblende is a highly complex mineral, made of combinations of up to 30 different elements. To isolate the unknown substances, of which only tiny amounts were present, the Curies were the first to use a new method of chemical analysis. They employed various standard (but sometimes demanding) chemical procedures to separate the different substances in pitchblende. For example, a particular element might dissolve in an acid, which they could pour off, leaving other elements behind in a sludge at the bottom of the pot. After the materials were separated into different types of compounds, the Curies used radiation measurements to trace the minute amount of unknown, radioactive element among the fractions that resulted.

Making repeated separations of the various substances in the pitchblende, Marie and Pierre used the Curie electrometer to identify the most radioactive fractions. They thus discovered that two fractions, one containing mostly bismuth and the other containing mostly barium, were strongly radioactive. In July 1898 the Curies published their conclusion: the bismuth fraction contained a new element. Chemically it acted almost exactly like bismuth, but since it was radioactive, it had to be something new. They named it "polonium" in honor of the country of Marie's birth. A second publication, in December 1898, explained their discovery in the barium fraction of another new element, which they named "radium" from the Latin word for ray. The Curies were close to reaching one of the highest goals that a scientist of the time could hope to achieve--placing new elements in the Periodic Table. While the chemical properties of the two new elements were completely dissimilar, they both had strong radioactivity.

page from Curie's lab notebook, 1898

A page from the Curies' lab notebook of 1898. On the left, in Pierre's hand, a sublimation procedure. On the right, in Marie's hand, chemical processing. (Photo ACJC)    Another picture

Read the Discovery Paper in which the Curies announced the existence of Radium...

TO CONVINCE THE SCIENTIFIC COMMUNITY of the existence of polonium and radium, and to complete the identification and establish the nature of the new elements, Marie set out to isolate them from the bismuth and barium with which they were mixed. Since the Municipal School storeroom would be inadequate to the task, the Curies moved their lab to an abandoned shed across the school courtyard. The shed, formerly a medical school dissecting room, was poorly outfitted and ventilated. It was not weathertight. She succeeded in separating the radium from the barium only with tremendous difficulty -- which would become central in the romantic legend of her life. She had to treat very large quantities of pitchblende, a ton of which the Curies received as a donation from the Austrian government. (The Austrians hoped she would find a use for a mineral their mines yielded as a waste byproduct.)

Luckily some help was available for the tedious labor of treating the pitchblende. They were able to collaborate with the Central Chemical Products Company, the firm that marketed Pierre's scientific instruments. Their colleague André Debierne cleverly adapted their standard lab techniques into larger-scale industrial processes. These processes isolated from the pitchblende materials with high concentrations of radium and polonium, which the Curies studied in detail in what she called the “miserable old shed.” In exchange for supplying chemical products and paying staff wages, the Central Chemical Products Company took a share of the radium salts extracted on its premises. The firm would later make a handsome profit by marketing these radium salts for medical and other uses.

The "miserable old shed" where radium was isolated.
The "miserable old shed" where radium was isolated.  [Another picture]

READ Curie's words
                                                                                   

 

Despite the industrial assistance the Curies received, it took Marie over three years to isolate one tenth of a gram of pure radium chloride. For reasons that would not be fully understood until the concept of radioactive decay was developed, Marie never succeeded in isolating polonium, which has a half-life of only 138 days.

 

 

Next:
Founding the Radium Industry

Also:
"Radium and Radioactivity" by Marie Curie
Discovery Paper announcing Radium
Periodic Table of Elements
Marie Curie and Her Legend
Radioactivity: The Unstable Nucleus and its Uses 

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