2011 Chemistry Nobel Prize Resources
The American Institute of Physics is proud to present resources on this year's Nobel Laureate in Chemistry, Daniel Shechtman from Technion–Israel Institute of Technology, Haifa, Israel for "the discovery of quasicrystals."
AIP is honored to count Professor Shechtman among its journal authors and has made the papers he has authored in AIP publications freely available until the end of 2011.
» Overview
» Press releases
» Access AIP Journal Articles by Daniel Shechtman
» Top twenty-five most highly cited AIP journal and magazine articles on quasicrystals
» Key journal articles and resources from the AIP Member Societies
Overview
The 2011 Nobel Prize in Chemistry was awarded to Daniel Shechtman, a distinguished professor at the Israel Institute of Technology in Haifa, "for the discovery of quasicrystals." The discovery was published in the American Physical Society's journal Physical Review Letters in 1984.
In all ordered materials composed of crystals, there are ordered, repeating arrays of atoms. A material's periodicity is created by translational and rotational symmetries which are repeated throughout the material.
Scientists use x-ray and electron diffraction to investigate the structure of a crystal. Professor Shechtman's measurements were instrumental in destroying the notion that it was periodicity that formed the diffraction pattern. Quasicrystals showed patterns, but no periodicity. But the type of symmetry discovered by Professor Shechtman was seemingly impossible according to what was then understood about the nature of crystallography. The spacing between atoms was too small to accommodate this so-called tenfold symmetry. Shechtman showed that the atoms in a crystal could be packed in a pattern that never repeated, yet had a well-defined symmetry.
These unique materials also have unique properties. In spite of their composition of mostly transition metals—whose properties generally include high thermal and electrical conductivities—quasicrystals often exhibit low thermal and electrical conductivities. In addition to their unique transport properties, these materials exhibit interesting physical properties as well. For example, their hardness is useful to strengthen materials, such as structural steel, and their low sticking coefficient makes them ideal as coatings for turbines.
At the time of the discovery, Professor Shechtman was on sabbatical from the National Institute of Standards and Technology (NIST), which at that time was the National Bureau of Standards (NBS).
The discovery forever changed the definition of crystallinity. Researchers came to realize that they could not know what physical parameters rigorously define a crystal.
Press releases
AIP Congratulates Daniel Shechtman, Winner of the 2011 Nobel Prize in Chemistry (10/5/11)
Access AIP Journal Articles by Daniel Shechtman, Recipient of the 2011 Nobel Prize in Chemistry
Discover every article that AIP has published from this Nobel Laureate. These articles are freely available at this time.
X-ray diffraction characterization of ternary artificial superlattices
I. Goldfarb, E. Zolotoyabko, and D. Shechtman
J. Appl. Phys. 74, 2501 (1993)
X-ray diffraction study of surface acoustic wave device under acoustic excitation
E. Zolotoyabko, E. Jacobsohn, D. Shechtman, B. Kantor, and J. Salzman
J. Appl. Phys. 73, 8647 (1993)
Moire fringe images of twin boundaries in chemical vapor deposited diamond
Dan Shechtman, Albert Feldman, Mark D. Vaudin, and John L. Hutchison
Appl. Phys. Lett. 62, 487 (1993)
Acoustic field study in layered structures by means of x-ray diffraction
E. Zolotoyabko, E. Jacobsohn, D. Shechtman, B. Kantor, and J. Salzman
J. Appl. Phys. 71, 3134 (1992)
On the model of metastable phase formation by a diffusion process
B. Grushko and D. Shechtman
J. Appl. Phys. 67, 2904 (1990)
Top twenty-five most highly cited AIP journal and magazine articles on quasicrystals
Formation of quasicrystals in bulk glass forming Zr-Cu-Ni-Al alloys
U. Köster, J. Meinhardt, S. Roos, and H. Liebertz
Appl. Phys. Lett. 69, 179 (1996)
High-strength materials produced by precipitation of icosahedral quasicrystals in bulk Zr–Ti–Cu–Ni–Al amorphous alloys
L. Q. Xing, J. Eckert, W. Löser, and L. Schultz
Appl. Phys. Lett. 74, 664 (1999)
Quasicrystals in a partially devitrified Zr65Al7.5Ni10Cu12.5Ag5 bulk metallic glass
M. W. Chen, T. Zhang, A. Inoue, A. Sakai, and T. Sakurai
Appl. Phys. Lett. 75, 1697 (1999)
Direct evidence for oxygen stabilization of icosahedral phase during crystallization of Zr65Cu27.5Al7.5 metallic glass
B. S. Murty, D. H. Ping, K. Hono, and A. Inoue
Appl. Phys. Lett. 76, 55 (2000)
Effect of cooling rate on the precipitation of quasicrystals from the Zr-Cu-Al-Ni-Ti amorphous alloy
L. Q. Xing, J. Eckert, W. Löser, and L. Schultz
Appl. Phys. Lett. 73, 2110 (1998)
Formation of icosahedral quasicrystalline phase in Zr70Ni10M20(M=Pd, Au, Pt) ternary metallic glasses
J. Saida, M. Matsushita, C. Li, and A. Inoue
Appl. Phys. Lett. 76, 3558 (2000)
Ductile quasicrystalline alloys
A. Inoue, T. Zhang, M. W. Chen, T. Sakurai, J. Saida, and M. Matsushita
Appl. Phys. Lett. 76, 967 (2000)
Nanoquasicrystallization of binary Zr–Pd metallic glasses
B. S. Murty, D. H. Ping, and K. Hono
Appl. Phys. Lett. 77, 1102 (2000)
As-cast quasicrystalline phase in a Zr-based multicomponent bulk alloy
U. Kühn, J. Eckert, N. Mattern, and L. Schultz
Appl. Phys. Lett. 77, 3176 (2000)
Formation of quasicrystals in Zr46.8Ti8.2Cu7.5Ni10Be27.5 bulk glass
N. Wanderka, M.-P. Macht, M. Seidel, S. Mechler, K. Ståhl, and J. Z. Jiang
Appl. Phys. Lett. 77, 3935 (2000)
Thermal and electrical transport properties of the single-phase quasicrystalline material: Al70.8Pd20.9Mn8.3
A. L. Pope, Terry M. Tritt, M. A. Chernikov, and M. Feuerbacher
Appl. Phys. Lett. 75, 1854 (1999)
Precipitation of icosahedral quasicrystalline phase in Hf65Al7.5Ni10Cu12.5Pd5 metallic glass
Chunfei Li, Junji Saida, Mitsuhide Matsushita, and Akihisa Inoue
Appl. Phys. Lett. 77, 528 (2000)
Structural transformation and localization during simulated nanoindentation of a noncrystalline metal film
Yunfeng Shi and Michael L. Falk
Appl. Phys. Lett. 86, 011914 (2005)
Formation of icosahedral phase from amorphous Zr65Al7.5Cu12.5Ni10Ag5 alloys
J. K. Lee, G. Choi, D. H. Kim, and W. T. Kim
Appl. Phys. Lett. 77, 978 (2000)
Nanoquasicrystalline phase produced by devitrification of Hf-Pd-Ni-Al metallic glass
D. V. Louzguine, M. S. Ko, and A. Inoue
Appl. Phys. Lett. 76, 3424 (2000)
Formation of a nanoquasicrystalline phase in Zr-Cu-Ti-Ni metallic glass
Dmitri V. Louzguine and Akihisa Inoue
Appl. Phys. Lett. 78, 1841 (2001)
Kinetic evidence for the structural similarity between a supercooled liquid and an icosahedral phase in Zr65Al7.5Ni10Cu12.5Ag5 bulk metallic glass
M. W. Chen, I. Dutta, T. Zhang, A. Inoue, and T. Sakurai
Appl. Phys. Lett. 79, 42 (2001)
Composition dependence of thermoelectric properties of AlPdRe icosahedral quasicrystals
K. Kiriharaand K. Kimura
J. Appl. Phys. 92, 979 (2002)
Large sonic band gaps in 12-fold quasicrystals
Yun Lai, Xiangdong Zhang, and Zhao-Qing Zhang
J. Appl. Phys. 91, 6191 (2002)
Effect of Ru substitution for Re on the thermoelectric properties of AlPdRe icosahedral quasicrystals
T. Nagata, K. Kirihara, and K. Kimura
J. Appl. Phys. 94, 6560 (2003)
Liquid to quasicrystal transition in bilayer water
Jessica C. Johnston, Noah Kastelowitz, and Valeria Molinero
J. Chem. Phys. 133, 154516 (2010)
Natural quasicrystal found in a museum specimen
Steven K. Blau
Phys. Today 62, August, 14 (2009)
Diffraction and Modeling Solve the Structure of Ytterbium-Cadmium Quasicrystals Mark Wilson
Phys. Today 60, March, 23 (2007)
Binary Quasicrystals Discovered That Are Stable and Icosahedral
Charles Day
Phys. Today 54, February, 17 (2001)
Forbidden Fivefold Symmetry May Indicate Quasicrystal Phase
Bertram Schwarzschild
Phys. Today 38, February, 17 (1985)
Key journal articles and resources from the AIP Member Societies
American Physical Society's Physical Review Letters
Metallic Phase with Long-Range Orientational Order and No Translational Symmetry
D.Shechtman, I. Blech, D. Gratias, and J.W. Cahn, Phys. Rev. Lett. 53, 1951 (1984)
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