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Color-Filtered STM

One of the most astounding inventions of the late 20th century, the scanning tunneling microscope, or STM, yields atomic-scale landscapes of electrically conducting surfaces such as metals. Now, researchers at the Colorado School of Mines have demonstrated a powerful new technique for filtering the images. Just as color filters make it easier to discern desired features in a photograph, "color-filtered STM" makes it easier to see desired atoms and chemical bonds on a surface. In the technique, electrons of different energies are analogous to different colors. Only electrons in desired energy ranges are allowed to jump or "tunnel" to the STM tip, to build up images of the atoms or chemical bonds of interest. In the image above, the left-hand side shows the atomic structure of the silicon (111) surface. Two different types of silicon atoms (marked in red and blue) exist at that surface (they differ by their position and the chemical-bonding environment on the surface). The atoms show up as bright spots in the two grayscale images on the right.

The next image is the kind that would be obtained with a conventional STM that has a metal tip. What shows up in this image are the atoms (shown in blue) that have the highest energy electrons associated with them.

The final image is a color- or energy-filtered image, in which the researchers have suppressed the blue atoms, and can now observe others that have electronic states at lower energy (shown in red). This silicon surface is actually a special case, in which the 'red' atoms actually lie sort of beneath the blue ones. Via energy filtering, researchers can thus "see through" the blue atoms and selectively image the red ones!

(Thanks to Peter Sutter of the Colorado School of Mines for the images and the caption.)

 

Source: P. Sutter, P. Zahl, E. Sutter, and J. E. Bernard, Physical Review Letters, 25 April 2003

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