Number 323, May 28, 1997 by Phillip F. Schewe and Ben Stein
AN AMORPHOUS SOLID BEHAVING LIKE A CRYSTAL.
Amorphous silicon, a solid in which atoms are arranged in a non-periodic jumble, rivals crystalline silicon for photovoltaic
applications. Unfortunately, atoms in the amorphous state often
have unfulfilled (dangling) bond sites which interfere with
electric currents. To cure this problem hydrogen atoms are
introduced into the solid to bind to these sites; but too much
hydrogen itself leads to a deterioration of electrical properties.
Now a collaboration of physicists from Cornell (Robert Pohl,
607-255-3303, pohl@msc.cornell.edu) and the National
Renewable Energy Labs (Golden, CO) has succeeded in
implanting a smaller, more judicious amount of hydrogen, greatly
improving the stability of the material and, in the process,
revealing something unexpected. If you shake a pure silicon
crystal (chilled to low temperatures) it will ring for an hour at
many different frequencies. In amorphous silicon, by contrast,
the tangled-atom nature of the sample quickly (in a second or
two) soaks up the vibrations at all different energies. In the
NREL hydrogenated amorphous silicon, however, some vibration
modes (the low-energy ones) persist for an hour, just as in
crystalline silicon. This as-yet-unexplained property gives the
researchers an experimental tool for exploring the role of
hydrogen in these solids and for studying amorphous solids in
general. For example, one can observe what happens to these
low-energy excitations as impurities are added to the material.
(Xiao Liu et al., upcoming article in Physical Review Letters,
probably June 9.)
THE EARLY FAINT SUN PARADOX goes as follows: 4
billion years ago the sun (its fusion fire not yet having worked up
to present levels) was 25-30% cooler than now. Terrestrial
temperatures would have been sub-freezing, precluding liquid
water. How then did life form in these early eras? Carl Sagan,
in a posthumous paper co-authored by Chris Chyba (Science, 22
May) suggests a possible scenario. Ultraviolet radiation from the
sun, they argue, would combine with existing methane to form
solid hydrocarbons in the upper atmosphere. This in turn would
shield ammonia (otherwise broken up by the UV) long enough
for the ammonia to produce a greenhouse warming adequate for
liquid water. Sagan and his interest in life in extreme
environments was the subject of a session yesterday at the
meeting of the American Geophysical Union in Baltimore.
According to David Morrison of NASA Ames, there are only
two places on Earth where life has not been found---on the
Antarctic ice sheet and in the upper atmosphere. Everywhere
else, whether in hot springs (even above boiling temperatures) or
a kilometer below the surface, life seems to thrive. One speaker,
Todd Stevens of the Pacific Northwest Lab, asserted that some
subsurface "rock-eating" microbes constituted an ecosystem
independent of photosynthesis and that their metabolism (in some
cases amounting to a biomass doubling time of millennia) was
perhaps the slowest of all life forms.
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