Evidence for a re-ionization era in the early universe has been glimpsed
in the form of a quasar spectrum exhibiting a paucity of radiation at
UV and shorter wavelengths.
Let's retrace some cosmological history. In the early years after the
big bang conditions were too hot for neutral atoms to form; protons
and electrons roamed independently in plasma form. Later, about 300,000
years after the big bang, things were cool enough for electrons and
protons to form neutral hydrogen, making the universe transparent to
visible light but opaque to higher-energy light which (if there were
much of it about, and there wasn't) would be absorbed by these same
H atoms. Later still the first stars and quasars started to pump out
UV light. This radiation was avidly absorbed by surrounding reservoirs
of neutral H, sometimes ionizing the atoms in the process.
As time passed more stars/galaxies/quasars formed, more UV was produced,
and more of the neutral H was being turned back into ions. At a certain
point, the great majority of H would be re-ionized. Since bare electrons
and protons cannot absorb light, UV photons could thereafter proceed
largely unhindered through the cosmos.
A new study of quasars (Becker et al., Los
Alamos preprint) made with the Sloan Digital Survey telescope looks
at this process happening; it shows that quasar spectra out to a redshift
of about 6 feature UV emission, but that the furthest-out (earliest
after the big bang) quasar yet glimpsed, at a redshift of 6.28, does
not, suggesting that this quasar was active in an epoch when neutral
H was still plentiful enough to choke off high energy radiation. Thus
a re-ionization era would seem to have occurred around Z=6, at a time
corresponding roughly to 800 million years after the big bang.