In a pyroelectric crystal held below a critical temperature (the Curie
temperature) heating or cooling causes distortions in the lattice of
atoms which in turn creates strong electric fields at the surface of
the crystal. James Brownridge of the State University of New York at
Binghamton (jdbjdb@binghamton.edu) and Stephen Shafroth of the University
of North Carolina (919-962-3015, shafroth@physics.unc.edu) have used
these electric fields to create stable, self-focused electron beams
with energies as high as 170 keV.
The energy conversion is not especially efficient: inputting watts
of heating energy produces only microwatts of output electron beam energy,
but this might not be important. Pyroelectric crystals (such as those
made of LiNbO3) are widely used as detectors of infrared
and THz radiation, but the discovery by Brownridge that they can also
be used to produce energetic electron beams if heated or cooled in dilute
gas atmospheres means that they can be used to produce x-ray fluorescence
for elemental analysis of complex materials, such as tree leaves, rocks,
air filters, blood samples, etc. Portable economical x-ray fluorescence
is now a real possibility. (Applied
Physics Letters, 12 Nov. 2001; also see Brownridge's website.)